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Ammine Complexes of Na-, Ag-, Mn-, and Zn-Azides

Müller, Thomas G. ; Buchner, Magnus R. ; Scheubeck, Thomas J. ; Korber, Nikolaus ; Kraus, Florian


The synthesis of ammine metal azides is achieved through a simple route in liquid ammonia solution. Azides of silver, sodium, manganese, and zinc were obtained as ammine complexes from liquid ammonia and the solid compounds were characterized. The NH3 solutions were investigated by means of NMR spectroscopy as well. The triamminesilver(I) azide as well as the unusual tetraamminesilver(I) and ...


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