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Potential dependence of surfactant adsorption at graphite electrode/deep eutectic solvent interface

Häckl, Katharina ; Li, Hua ; Aldous, Iain ; Tsui, Terrence ; Kunz, Werner ; Abbott, Andrew P. ; Warr, Gregory ; Atkin, Rob


Atomic force microscopy and cyclic voltammetry are used to probe how ionic surfactant adsorbed layer structure affects redox processes at deep eutectic solvent (DES)/graphite interfaces. Unlike its behavior in water, sodium dodecyl sulfate (SDS) in DESs only adsorbs as a complete layer of hemicylindrical hemimicelles far above its critical micelle concentration (CMC). Near the CMC it forms a ...


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