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Photocatalytic activation of alkyl chlorides by assembly-promoted single electron transfer in microheterogenous solutions

Giedyk, Maciej ; Narobe, Rok ; Weiss, Sophia ; Touraud, Didier ; Kunz, Werner ; König, Burkhard


Photocatalytic activation of alkyl carbon-chlorine bonds has constantly proven difficult due to the high energies needed to cleave this stable bond. Here a surfactant-based photocatalytic system is used, allowing for the radical dehalogenation and subsequent reactivity of unactivated alkyl chlorides. Photoredox catalysis has developed into a powerful tool for the synthesis of organic compounds ...


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