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Minisci C-H Alkylation of Heteroarenes Enabled by Dual
Photoredox/Bromide Catalysis in Micellar Solutions

Giedyk, Maciej ; Santos, Marilia S. ; Cybularczyk-Cecotka, Martyna ; König, Burkhard


Aromatic heterocycles are omnipresent structural motifs in various natural products, pharmaceuticals and agrochemicals. This work describes a photocatalytic Minisci-type C-H functionalization of heteroarenes with non-activated alkyl bromides. The reaction avoids stoichiometric radical-promoters, oxidants, or acids, and is conducted using blue LEDs as the light source. The reactive carbon-centered ...


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