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Complexation behaviour of LiCl and LiPF6 – model studies in the solid-state and in solution using a bidentate picolyl-based ligand

Espinosa-Jalapa, N. A. ; Berg, N. ; Seidl, M. ; Shenderovich, Ilya G. ; Gschwind, Ruth M. ; Bauer, J. O.



Abstract

Structural knowledge on ubiquitous lithium salts in solution and in the crystalline state is of paramount importance for our understanding of many chemical reactions and of the electrolyte behaviour in lithium ion batteries. A bulky bidentate Si-based ligand (6) was used to create simplified model systems suitable for correlating structures of LiCl and LiPF6 complexes in the solid-state and in ...

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