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Spotlight on Alkali Metals: The Structural Chemistry of Alkali Metal Thallides

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Gärtner, Stefanie
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Date of publication of this fulltext: 13 Jan 2021 14:56


Alkali metal thallides go back to the investigative works of Eduard Zintl about base metals in negative oxidation states. In 1932, he described the crystal structure of NaTl as the first representative for this class of compounds. Since then, a bunch of versatile crystal structures has been reported for thallium as electronegative element in intermetallic solid state compounds. For combinations ...


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