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On the Reactivity of NHCtBuAuCl towards Rb6Cs6Si17: The First Gold‐Silicon Cluster [(NHCtBuAu)6(η2‐Si4)]Cl2·7NH3 and an Imide Capped Gold Triangle (NHCtBuAu)3NHCl

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Tiefenthaler, Susanne ; Streitferdt, Verena ; Baumann, Josef ; Gärtner, Stefanie ; Gschwind, Ruth Maria ; Korber, Nikolaus
License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 27 Jan 2021 08:38

This publication is part of the DEAL contract with Wiley.


Crystals of the two new compounds ((NHCAu)-Au-tBu)(3)NHCl and [((NHCAu)-Au-tBu)(6)(eta(2)-Si-4)]Cl-2 center dot 7NH(3)could be isolated from the reaction of Rb(6)Cs(6)Si(17)with (NHCAuCl)-Au-tBu in the presence of [2.2.2]-cryptand in liquid ammonia. Both compounds were characterized by single-crystal X-ray diffraction and crystallize trigonally without any alkali metals or chelating ligands. ...


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