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Iron-Gallium and Cobalt-Gallium Tetraphosphido Complexes

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Ziegler, Christoph ; Hennersdorf, Felix ; Weigand, Jan J. ; Wolf, Robert
License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 27 Jan 2021 09:21

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The synthesis and characterization of two heterobimetallic complexes [K([18]crown-6){(eta(4)-C14H10)Fe(mu-eta(4):eta(2)-P-4)Ga(nacnac)}] (1) (C14H10 = anthracene) and [K(dme)(2){(eta(4)-C14H10)Co(mu-eta(4):eta(2)-P-4)Ga(nacnac)}] (2) with strongly reduced P-4 units is reported. Compounds 1 and 2 are prepared by reaction of the gallium(III) complex [(nacnac)Ga(eta(2)-P-4)] (nacnac = ...


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