Iron-Gallium and Cobalt-Gallium Tetraphosphido Complexes

URN to cite this document:: urn:nbn:de:bvb:355-epub-446144
DOI to cite this document:: 10.5283/epub.44614

Ziegler, Christoph ; Hennersdorf, Felix

; Weigand, Jan J.

; Wolf, Robert

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Date of publication of this fulltext: 27 Jan 2021 09:21

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Abstract

The synthesis and characterization of two heterobimetallic complexes [K([18]crown-6){(eta(4)-C14H10)Fe(mu-eta(4):eta(2)-P-4)Ga(nacnac)}] (1) (C14H10 = anthracene) and [K(dme)(2){(eta(4)-C14H10)Co(mu-eta(4):eta(2)-P-4)Ga(nacnac)}] (2) with strongly reduced P-4 units is reported. Compounds 1 and 2 are prepared by reaction of the gallium(III) complex [(nacnac)Ga(eta(2)-P-4)] (nacnac = ...