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Ultrafast Charge Separation in Bilayer WS2/Graphene Heterostructure Revealed by Time- and Angle-Resolved Photoemission Spectroscopy
Krause, Razvan, Chávez-Cervantes, Mariana, Aeschlimann, Sven, Forti, Stiven, Fabbri, Filippo
, Rossi, Antonio, Coletti, Camilla
, Cacho, Cephise, Zhang, Yu
, Majchrzak, Paulina Ewa
, Chapman, Richard T., Springate, Emma
and Gierz, Isabella
(2021)
Ultrafast Charge Separation in Bilayer WS2/Graphene Heterostructure Revealed by Time- and Angle-Resolved Photoemission Spectroscopy.
Frontiers in Physics 2021 (9), p. 668149.
(Submitted)
Date of publication of this fulltext: 01 Jun 2021 15:15
Article
DOI to cite this document: 10.5283/epub.44995
Abstract
Efficient light harvesting devices need to combine strong absorption in the visible spectral range with efficient ultrafast charge separation. These features commonly occur in novel ultimately thin van der Waals heterostructures with type II band alignment. Recently, ultrafast charge separation was also observed in monolayer WS2/graphene heterostructures with type I band alignment. Here we use ...
Efficient light harvesting devices need to combine strong absorption in the visible spectral range with efficient ultrafast charge separation. These features commonly occur in novel ultimately thin van der Waals heterostructures with type II band alignment. Recently, ultrafast charge separation was also observed in monolayer WS2/graphene heterostructures with type I band alignment. Here we use time- and angle-resolved photoemission spectroscopy to show that ultrafast charge separation also occurs at the interface between bilayer WS2 and graphene indicating that the indirect band gap of bilayer WS2 does not affect the charge transfer to the graphene layer. The microscopic insights gained in the present study will turn out to be useful for the design of novel optoelectronic devices.
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| Item type | Article | ||||
| Journal or Publication Title | Frontiers in Physics | ||||
| Publisher: | Frontiers | ||||
|---|---|---|---|---|---|
| Open Access Type: | Gold (with APC) | ||||
| Place of Publication: | LAUSANNE | ||||
| Volume: | 2021 | ||||
| Number of Issue or Book Chapter: | 9 | ||||
| Page Range: | p. 668149 | ||||
| Date | 29 April 2021 | ||||
| Institutions | Physics > Institute of Experimental and Applied Physics > Prof. Dr. Isabella Gierz | ||||
| Identification Number |
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| Keywords | EXCITON BINDING-ENERGY; BANDGAP RENORMALIZATION; GRAPHENE; LAYERS; TMD; graphene; van der Waals heterostructures; tr-ARPES; ultrafast charge transfer; photovoltaics | ||||
| Dewey Decimal Classification | 500 Science > 530 Physics | ||||
| Status | Submitted | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-449955 | ||||
| Item ID | 44995 |
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