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Krause, Razvan ; Chávez-Cervantes, Mariana ; Aeschlimann, Sven ; Forti, Stiven ; Fabbri, Filippo ; Rossi, Antonio ; Coletti, Camilla ; Cacho, Cephise ; Zhang, Yu ; Majchrzak, Paulina Ewa ; Chapman, Richard T. ; Springate, Emma ; Gierz, Isabella

Ultrafast Charge Separation in Bilayer WS2/Graphene Heterostructure Revealed by Time- and Angle-Resolved Photoemission Spectroscopy

Krause, Razvan, Chávez-Cervantes, Mariana, Aeschlimann, Sven, Forti, Stiven, Fabbri, Filippo , Rossi, Antonio, Coletti, Camilla , Cacho, Cephise, Zhang, Yu , Majchrzak, Paulina Ewa , Chapman, Richard T., Springate, Emma and Gierz, Isabella (2021) Ultrafast Charge Separation in Bilayer WS2/Graphene Heterostructure Revealed by Time- and Angle-Resolved Photoemission Spectroscopy. Frontiers in Physics 2021 (9), p. 668149. (Submitted)

Date of publication of this fulltext: 01 Jun 2021 15:15
Article
DOI to cite this document: 10.5283/epub.44995


Abstract

Efficient light harvesting devices need to combine strong absorption in the visible spectral range with efficient ultrafast charge separation. These features commonly occur in novel ultimately thin van der Waals heterostructures with type II band alignment. Recently, ultrafast charge separation was also observed in monolayer WS2/graphene heterostructures with type I band alignment. Here we use ...

Efficient light harvesting devices need to combine strong absorption in the visible spectral range with efficient ultrafast charge separation. These features commonly occur in novel ultimately thin van der Waals heterostructures with type II band alignment. Recently, ultrafast charge separation was also observed in monolayer WS2/graphene heterostructures with type I band alignment. Here we use time- and angle-resolved photoemission spectroscopy to show that ultrafast charge separation also occurs at the interface between bilayer WS2 and graphene indicating that the indirect band gap of bilayer WS2 does not affect the charge transfer to the graphene layer. The microscopic insights gained in the present study will turn out to be useful for the design of novel optoelectronic devices.



Involved Institutions


Details

Item typeArticle
Journal or Publication TitleFrontiers in Physics
Publisher:Frontiers
Open Access Type:Gold (with APC)
Place of Publication:LAUSANNE
Volume:2021
Number of Issue or Book Chapter:9
Page Range:p. 668149
Date29 April 2021
InstitutionsPhysics > Institute of Experimental and Applied Physics > Prof. Dr. Isabella Gierz
Identification Number
ValueType
10.3389/fphy.2021.668149DOI
KeywordsEXCITON BINDING-ENERGY; BANDGAP RENORMALIZATION; GRAPHENE; LAYERS; TMD; graphene; van der Waals heterostructures; tr-ARPES; ultrafast charge transfer; photovoltaics
Dewey Decimal Classification500 Science > 530 Physics
StatusSubmitted
RefereedYes, this version has been refereed
Created at the University of RegensburgYes
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-449955
Item ID44995

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