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Svejstrup, Thomas D. ; Chatterjee, Anamitra ; Schekin, Denis ; Wagner, Thomas ; Zach, Julia ; Johansson, Magnus J. ; Bergonzini, Giulia ; König, Burkhard

Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors

Svejstrup, Thomas D., Chatterjee, Anamitra, Schekin, Denis, Wagner, Thomas, Zach, Julia, Johansson, Magnus J., Bergonzini, Giulia und König, Burkhard (2021) Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors. ChemPhotoChem 5, S. 808-814.

Veröffentlichungsdatum dieses Volltextes: 14 Mai 2021 04:24
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.45688


Zusammenfassung

In the last decade, visible-light photoredox catalysis has evolved into a versatile tool in organic synthesis. However, most reports have used homemade photoreactors in their design and optimisation of new methods, complicating the reproducibility of some transformations. To improve reproducibility and efficiency, laboratory photoreactors have been developed and commercialized. Herein we report a ...

In the last decade, visible-light photoredox catalysis has evolved into a versatile tool in organic synthesis. However, most reports have used homemade photoreactors in their design and optimisation of new methods, complicating the reproducibility of some transformations. To improve reproducibility and efficiency, laboratory photoreactors have been developed and commercialized. Herein we report a comparison of four commercially available photoreactors in six mechanistically distinct photoredox reactions focusing on the difference in product yields and kinetics as well as the factors which lead to these differences, including reaction temperature and light intensity.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftChemPhotoChem
Verlag:Wiley
Ort der Veröffentlichung:WEINHEIM
Band:5
Seitenbereich:S. 808-814
Datum4 Mai 2021
InstitutionenChemie und Pharmazie > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identifikationsnummer
WertTyp
10.1002/cptc.202100059DOI
Stichwörter / KeywordsRADICAL-ADDITION; PHOTOREDOX; CATALYSIS; ARENES; light intensity; photoredox catalysis; photoreactor; reaction temperature; reproducibility
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 540 Chemie
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenZum Teil
URN der UB Regensburgurn:nbn:de:bvb:355-epub-456889
Dokumenten-ID45688

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