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Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors
Svejstrup, Thomas D., Chatterjee, Anamitra, Schekin, Denis, Wagner, Thomas, Zach, Julia, Johansson, Magnus J., Bergonzini, Giulia and König, Burkhard
(2021)
Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors.
ChemPhotoChem 5, pp. 808-814.
Date of publication of this fulltext: 14 May 2021 04:24
Article
DOI to cite this document: 10.5283/epub.45688
Abstract
In the last decade, visible-light photoredox catalysis has evolved into a versatile tool in organic synthesis. However, most reports have used homemade photoreactors in their design and optimisation of new methods, complicating the reproducibility of some transformations. To improve reproducibility and efficiency, laboratory photoreactors have been developed and commercialized. Herein we report a ...
In the last decade, visible-light photoredox catalysis has evolved into a versatile tool in organic synthesis. However, most reports have used homemade photoreactors in their design and optimisation of new methods, complicating the reproducibility of some transformations. To improve reproducibility and efficiency, laboratory photoreactors have been developed and commercialized. Herein we report a comparison of four commercially available photoreactors in six mechanistically distinct photoredox reactions focusing on the difference in product yields and kinetics as well as the factors which lead to these differences, including reaction temperature and light intensity.
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Details
| Item type | Article | ||||
| Journal or Publication Title | ChemPhotoChem | ||||
| Publisher: | Wiley | ||||
|---|---|---|---|---|---|
| Place of Publication: | WEINHEIM | ||||
| Volume: | 5 | ||||
| Page Range: | pp. 808-814 | ||||
| Date | 4 May 2021 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Identification Number |
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| Keywords | RADICAL-ADDITION; PHOTOREDOX; CATALYSIS; ARENES; light intensity; photoredox catalysis; photoreactor; reaction temperature; reproducibility | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Partially | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-456889 | ||||
| Item ID | 45688 |
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