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Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors
Svejstrup, Thomas D., Chatterjee, Anamitra, Schekin, Denis, Wagner, Thomas, Zach, Julia, Johansson, Magnus J., Bergonzini, Giulia und König, Burkhard
(2021)
Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors.
ChemPhotoChem 5, S. 808-814.
Veröffentlichungsdatum dieses Volltextes: 14 Mai 2021 04:24
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.45688
Zusammenfassung
In the last decade, visible-light photoredox catalysis has evolved into a versatile tool in organic synthesis. However, most reports have used homemade photoreactors in their design and optimisation of new methods, complicating the reproducibility of some transformations. To improve reproducibility and efficiency, laboratory photoreactors have been developed and commercialized. Herein we report a ...
In the last decade, visible-light photoredox catalysis has evolved into a versatile tool in organic synthesis. However, most reports have used homemade photoreactors in their design and optimisation of new methods, complicating the reproducibility of some transformations. To improve reproducibility and efficiency, laboratory photoreactors have been developed and commercialized. Herein we report a comparison of four commercially available photoreactors in six mechanistically distinct photoredox reactions focusing on the difference in product yields and kinetics as well as the factors which lead to these differences, including reaction temperature and light intensity.
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Details
| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | ChemPhotoChem | ||||
| Verlag: | Wiley | ||||
|---|---|---|---|---|---|
| Ort der Veröffentlichung: | WEINHEIM | ||||
| Band: | 5 | ||||
| Seitenbereich: | S. 808-814 | ||||
| Datum | 4 Mai 2021 | ||||
| Institutionen | Chemie und Pharmazie > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Identifikationsnummer |
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| Stichwörter / Keywords | RADICAL-ADDITION; PHOTOREDOX; CATALYSIS; ARENES; light intensity; photoredox catalysis; photoreactor; reaction temperature; reproducibility | ||||
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden | Zum Teil | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-456889 | ||||
| Dokumenten-ID | 45688 |
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