Direkt zum Inhalt

Svejstrup, Thomas D. ; Chatterjee, Anamitra ; Schekin, Denis ; Wagner, Thomas ; Zach, Julia ; Johansson, Magnus J. ; Bergonzini, Giulia ; König, Burkhard

Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors

Svejstrup, Thomas D., Chatterjee, Anamitra, Schekin, Denis, Wagner, Thomas, Zach, Julia, Johansson, Magnus J., Bergonzini, Giulia and König, Burkhard (2021) Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors. ChemPhotoChem 5, pp. 808-814.

Date of publication of this fulltext: 14 May 2021 04:24
Article
DOI to cite this document: 10.5283/epub.45688


Abstract

In the last decade, visible-light photoredox catalysis has evolved into a versatile tool in organic synthesis. However, most reports have used homemade photoreactors in their design and optimisation of new methods, complicating the reproducibility of some transformations. To improve reproducibility and efficiency, laboratory photoreactors have been developed and commercialized. Herein we report a ...

In the last decade, visible-light photoredox catalysis has evolved into a versatile tool in organic synthesis. However, most reports have used homemade photoreactors in their design and optimisation of new methods, complicating the reproducibility of some transformations. To improve reproducibility and efficiency, laboratory photoreactors have been developed and commercialized. Herein we report a comparison of four commercially available photoreactors in six mechanistically distinct photoredox reactions focusing on the difference in product yields and kinetics as well as the factors which lead to these differences, including reaction temperature and light intensity.



Involved Institutions


Details

Item typeArticle
Journal or Publication TitleChemPhotoChem
Publisher:Wiley
Place of Publication:WEINHEIM
Volume:5
Page Range:pp. 808-814
Date4 May 2021
InstitutionsChemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number
ValueType
10.1002/cptc.202100059DOI
KeywordsRADICAL-ADDITION; PHOTOREDOX; CATALYSIS; ARENES; light intensity; photoredox catalysis; photoreactor; reaction temperature; reproducibility
Dewey Decimal Classification500 Science > 540 Chemistry & allied sciences
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgPartially
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-456889
Item ID45688

Export bibliographical data

Owner only: item control page

nach oben