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Synthesis and Characterization of Bidentate Isonitrile Iron Complexes

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Till, Marion ; Kelly, John A. ; Ziegler, Christoph G. P. ; Wolf, Robert ; Guo, Tianao ; Ringenberg, Mark R. ; Lutsker, Eugen ; Reiser, Oliver
Date of publication of this fulltext: 18 May 2021 07:13


Divalent iron complexes trans-[FeBr2(BINC)2], [Cp*FeCl(BINC)] (Cp* = Me5C5) and [FeBr2(CNAr3NC)2] with chelat-ing bis(isonitrile) ligands BINC (bis(2-isocyanophenyl)phenylphosphonate) and CNAr3NC (2,2’’-diisocyano-3,5,3’’,5’’tetramethyl-1,1’:3’,1’’-terphenyl) have been prepared and characterized. Their subsequent reduction yields di- and trinuclear compounds [Fe3(BINC)6], [Cp*Fe(BINC)]2, ...


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