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Synthesis and Characterization of Bidentate Isonitrile Iron Complexes

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Till, Marion ; Kelly, John A. ; Ziegler, Christoph G. P. ; Wolf, Robert ; Guo, Tianao ; Ringenberg, Mark R. ; Lutsker, Eugen ; Reiser, Oliver
Date of publication of this fulltext: 18 May 2021 07:13


The divalent iron complexes trans-[FeBr2(BINC)(2)], [Cp*FeCI(BINC)] (Cp* = Me5C5), and [FeBr2(CNAr3NC)(2)] with the chelating bis(isonitrile) ligands BINC (bis(2-isocyanophenyl)phenylphosphonate) and CNAr3 NC (2,2 ''-diisocyano-3,5,3 '',5 '' tetra-methyl-1,1':3',1 ''-terphenyl) have been prepared and characterized. Their subsequent reduction yields the di- and trinuclear compounds ...


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