Synthesis and Characterization of Bidentate Isonitrile Iron Complexes

URN to cite this document:: urn:nbn:de:bvb:355-epub-457078
DOI to cite this document:: 10.5283/epub.45707

Till, Marion ; Kelly, John A. ; Ziegler, Christoph G. P. ; Wolf, Robert

; Guo, Tianao ; Ringenberg, Mark R. ; Lutsker, Eugen ; Reiser, Oliver

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Date of publication of this fulltext: 18 May 2021 07:13

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Abstract

The divalent iron complexes trans-[FeBr2(BINC)(2)], [Cp*FeCI(BINC)] (Cp* = Me5C5), and [FeBr2(CNAr3NC)(2)] with the chelating bis(isonitrile) ligands BINC (bis(2-isocyanophenyl)phenylphosphonate) and CNAr3 NC (2,2 ''-diisocyano-3,5,3 '',5 '' tetra-methyl-1,1':3',1 ''-terphenyl) have been prepared and characterized. Their subsequent reduction yields the di- and trinuclear compounds ...