Aufbau‐ und Abbaureaktionen von weißem Phosphor induziert durch N‐heterocyclische Carbenkomplexe von Nickel(0). Aggregation and Degradation of White Phosphorus Mediated by N‐Heterocyclic Carbene Nickel(0) Complexes

URN to cite this document:: urn:nbn:de:bvb:355-epub-457119
DOI to cite this document:: 10.5283/epub.45711

Hierlmeier, Gabriele ; Coburger, Peter

; Leest, Nicolaas P.

; de Bruin, Bas

; Wolf, Robert

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Date of publication of this fulltext: 18 May 2021 05:11

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Abstract

The reaction of zerovalent nickel compounds with white phosphorus (P-4) is a barely explored route to binary nickel phosphide clusters. Here, we show that coordinatively and electronically unsaturated N-heterocyclic carbene (NHC) nickel(0) complexes afford unusual cluster compounds with P-1, P-3, P-5 and P-8 units. Using [Ni(IMes)(2)] [IMes=1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene], ...