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[3+2]‐Fragmentierung von Pentaphosphidoliganden durch Cyanid. [3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide†

URN to cite this document:
urn:nbn:de:bvb:355-epub-457226
DOI to cite this document:
10.5283/epub.45722
Hoidn, Christian M. ; Maier, Thomas M. ; Trabitsch, Karolina ; Weigand, Jan J. ; Wolf, Robert
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License: Creative Commons Attribution Non-commercial 4.0
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License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 18 May 2021 04:47


Abstract

The activation of white phosphorus (P4) by transition‐metal complexes has been studied for several decades, but the functionalization and release of the resulting (organo)phosphorus ligands has rarely been achieved. Herein we describe the formation of rare diphosphan‐1‐ide anions from a P5 ligand by treatment with cyanide. Cobalt diorganopentaphosphido complexes have been synthesized by a ...

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