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Functionalization of Pentaphosphorus Cations by Complexation

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Adhikari, Anup K. ; Ziegler, Christoph G. P. ; Schwedtmann, Kai ; Taube, Clemens ; Weigand, Jan J. ; Wolf, Robert
License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 18 May 2021 04:36


The chemistry of polyphosphorus cations has rapidly developed in recent years, but their coordination behavior has remained mostly unexplored. Herein, we describe the reactivity of [P5R2]+ cations with cyclopentadienyl metal complexes. The reaction of [CpArFe(μ‐Br)]2 (CpAr=C5(C6H4‐4‐Et)5) with [P5R2][GaCl4] (R=iPr and 2,4,6‐Me3C6H2 (Mes)) afforded bicyclo[1.1.0]pentaphosphanes (1‐R, R=iPr and ...


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