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Spin Transition in Arrays of Gold Nanoparticles and Spin Crossover Molecules

Devid, Edwin J. ; Martinho, Paulo N. ; Kamalakar, M. Venkata ; Šalitroš, Ivan ; Prendergast, Úna ; Dayen, Jean-François ; Meded, Velimir ; Lemma, Tibebe ; González-Prieto, Rodrigo ; Evers, Ferdinand ; Keyes, Tia E. ; Ruben, Mario ; Doudin, Bernard ; van der Molen, Sense Jan


We investigate if the functionality of spin crossover molecules is preserved when they are assembled into an interfacial device structure. Specifically, we prepare and investigate gold nanoparticle arrays, into which room-temperature spin crossover molecules are introduced, more precisely, [Fe(AcS-BPP)2](ClO4)2, where AcS-BPP = (S)-(4-{[2,6-(dipyrazol-1-yl)pyrid 4-yl]ethynyl}phenyl)ethanethioate ...


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