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Phosphorus-Containing Tetrahedranes: Synthesis and Reactivity Studies

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Hierlmeier, Gabriele
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Date of publication of this fulltext: 01 Jun 2022 05:49

Abstract (English)

This thesis primarily reports on the synthesis and reactivity of phosphorus-containing tetrahedranes. Chapter 1 reviews the chemistry of p-block tetrahedranes, covering the synthesis of both organic tetrahedranes - exemplified by tetra-tert-butyltetrahedrane - and inorganic tetrahedranes such as white phosphorus (P₄). Chapter 2 describes the release of P₂ units from a nickel butterfly complex, ...


Translation of the abstract (German)

Diese Dissertation behandelt hauptsächlich die Synthese und Reaktivität von phosphorhaltigen Tetrahedranen. Kapitel 1 gibt einen Überblick über die Chemie von p-Block Tetrahedranen und beschreibt unter anderem die Synthese des organischen Tetrahedrans Tetra-tert-butyltetrahedran und anorganischen Tetrahedranen wie z.B. weißem Phosphor. In Kapitel 2 wird die Freisetzung von P₂-Fragmenten durch ...


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