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Functional Group Variation in tert ‐Butyldiphenylsilanes (TBDPS): Syntheses, Reactivities, and Effects on the Intermolecular Interaction Pattern in the Molecular Crystalline State

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Bauer, Jonathan O. ; Espinosa‐Jalapa, Noel Angel ; Fontana, Nicolo ; Götz, Tobias ; Falk, Alexander
License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 22 Jun 2021 05:17

This publication is part of the DEAL contract with Wiley.


We present the preparation of tert-butyldiphenylsilanes differing in one functional group. The molecular structures of the phenyl (3), methoxy (4), and amino derivatives (5) were elucidated by single-crystal X-ray diffraction analysis and their crystal packing investigated by Hirshfeld surface analysis along with 2D fingerprint plots. In the all-C derivative 3, the high symmetry dependence of the ...


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