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Expedient Hydrofunctionalisation of Carbonyls and Imines Initiated by Phosphacyclohexadienyl Anions
Margeson, Matthew J., Seeberger, Felix, Kelly, John A., Leitl, Julia, Coburger, Peter
, Szlosek, Robert, Müller, Christian und Wolf, Robert
(2021)
Expedient Hydrofunctionalisation of Carbonyls and Imines Initiated by Phosphacyclohexadienyl Anions.
ChemCatChem 13, S. 3761-3764.
Veröffentlichungsdatum dieses Volltextes: 22 Jun 2021 06:08
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.46068
Zusammenfassung
The ability of phosphacyclohexadienyl anions [Li(1-R-PC5Ph3H2)] [R=Me (1 a), nBu (1 b), tBu (1 c), Ph (1 d) and CH2SiMe3 (1 e)] to initiate hydrofunctionalisation reactions was investigated and compared with simple, commercially available compounds, such as LiOtBu, KOtBu and nBuLi. All compounds are expedient catalysts for the hydroboration of a wide scope of substrates, ranging from aldehydes to ...
The ability of phosphacyclohexadienyl anions [Li(1-R-PC5Ph3H2)] [R=Me (1 a), nBu (1 b), tBu (1 c), Ph (1 d) and CH2SiMe3 (1 e)] to initiate hydrofunctionalisation reactions was investigated and compared with simple, commercially available compounds, such as LiOtBu, KOtBu and nBuLi. All compounds are expedient catalysts for the hydroboration of a wide scope of substrates, ranging from aldehydes to imines and esters. In the hydroboration of carbon dioxide, however, only our system was observed to efficiently produce the desired methanol equivalents.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | ChemCatChem | ||||
| Verlag: | Wiley | ||||
|---|---|---|---|---|---|
| Ort der Veröffentlichung: | WEINHEIM | ||||
| Band: | 13 | ||||
| Seitenbereich: | S. 3761-3764 | ||||
| Datum | 30 Mai 2021 | ||||
| Institutionen | Chemie und Pharmazie > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf | ||||
| Projekte |
Gefördert von:
Deutsche Forschungsgemeinschaft (DFG)
(390741761)
| ||||
| Identifikationsnummer |
| ||||
| Stichwörter / Keywords | MAIN-GROUP ELEMENTS; CATALYTIC HYDROBORATION; HYDROSILYLATION; KETONES; REDUCTION; ALDEHYDES; Carbon dioxide reduction; Hydrofunctionalisation; Main group catalysis; Phosphinine; Phosphorus | ||||
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden | Zum Teil | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-460681 | ||||
| Dokumenten-ID | 46068 |
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