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Molecular Switch Controlled by Pulsed Bias Voltages

Meded, Velimir ; Bagrets, Alexei ; Arnold, Andreas ; Evers, Ferdinand


Recent experiments have shown that the current–voltage characteristics (I–V) of BPDN-DT (bipyridyl-dinitro oligophenylene-ethynylene dithiol) can be switched in a very controlled manner between “on” and “off” traces by applying a pulse in a bias voltage, Vbias. Here, the polaron formation energies are calculated to check a frequently held belief, namely, that the polaron formation can explain the ...


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