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Cerium-photocatalyzed aerobic oxidation of benzylic alcohols
to aldehydes and ketones
Yedase, Girish Suresh, Kumar, Sumit, Stahl, Jessica, König, Burkhard
and Yatham, Veera Reddy
(2021)
Cerium-photocatalyzed aerobic oxidation of benzylic alcohols
to aldehydes and ketones. Beilstein Journal of Organic Chemistry 17, pp. 1727-1732.
Date of publication of this fulltext: 27 Jul 2021 07:42
Article
Abstract
We have developed a cerium-photocatalyzed aerobic oxidation of primary and secondary benzylic alcohols to aldehydes and ketones using inexpensive CeCl3 center dot 7H(2)O as photocatalyst and air oxygen as the terminal oxidant.
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| Item type | Article | ||||
| Journal or Publication Title | Beilstein Journal of Organic Chemistry | ||||
| Publisher: | BEILSTEIN-INSTITUT | ||||
|---|---|---|---|---|---|
| Place of Publication: | FRANKFURT AM MAIN | ||||
| Volume: | 17 | ||||
| Page Range: | pp. 1727-1732 | ||||
| Date | 23 July 2021 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Identification Number |
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| Keywords | TRANSITION-METAL-FREE; SELECTIVE OXIDATION; HIGHLY EFFICIENT; DIMETHYL-SULFOXIDE; CATALYST; PHOTOOXIDATION; OXYGEN; GREEN; TIO2; MECHANISM; alcohol; aldehydes; cerium; oxidation; ketones; visible light | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Partially | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-464330 | ||||
| Item ID | 46433 |
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