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Yedase, Girish Suresh ; Kumar, Sumit ; Stahl, Jessica ; König, Burkhard ; Yatham, Veera Reddy

Cerium-photocatalyzed aerobic oxidation of benzylic alcohols
to aldehydes and ketones

Yedase, Girish Suresh, Kumar, Sumit, Stahl, Jessica, König, Burkhard and Yatham, Veera Reddy (2021) Cerium-photocatalyzed aerobic oxidation of benzylic alcohols
to aldehydes and ketones.
Beilstein Journal of Organic Chemistry 17, pp. 1727-1732.

Date of publication of this fulltext: 27 Jul 2021 07:42
Article


Abstract

We have developed a cerium-photocatalyzed aerobic oxidation of primary and secondary benzylic alcohols to aldehydes and ketones using inexpensive CeCl3 center dot 7H(2)O as photocatalyst and air oxygen as the terminal oxidant.



Involved Institutions


Details

Item typeArticle
Journal or Publication TitleBeilstein Journal of Organic Chemistry
Publisher:BEILSTEIN-INSTITUT
Place of Publication:FRANKFURT AM MAIN
Volume:17
Page Range:pp. 1727-1732
Date23 July 2021
InstitutionsChemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number
ValueType
10.3762/bjoc.17.121DOI
KeywordsTRANSITION-METAL-FREE; SELECTIVE OXIDATION; HIGHLY EFFICIENT; DIMETHYL-SULFOXIDE; CATALYST; PHOTOOXIDATION; OXYGEN; GREEN; TIO2; MECHANISM; alcohol; aldehydes; cerium; oxidation; ketones; visible light
Dewey Decimal Classification500 Science > 540 Chemistry & allied sciences
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgPartially
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-464330
Item ID46433

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