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Microsolvation of porphine molecules in superfluid helium nanodroplets as revealed by optical line shape at the electronic origin

Fischer, J. ; Fuchs, S. ; Slenczka, A. ; Karra, M. ; Friedrich, B.


We investigate the line shape at the electronic origin of single porphine molecules doped into super fluid helium droplets as a function of the droplet size. Helium droplets comprised of less than 105 atoms are generated from an expansion of gaseous helium, while droplets with more than 105 atoms originate from liquid helium. In contrast to our recent study on phthalocyanine, porphine is found to ...


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