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Flavin Dibromide as an Efficient Sensitizer for Photooxidation of Sulfides

Dang, Can ; Zhu, Lijuan ; Guo, Huimin ; Xia, Hongyu ; Zhao, Jianzhang ; Dick, Bernhard



Abstract

Flavin derivatives (FLs) are the building blocks and functional groups within many enzymes that absorb strongly in the visible light region and are redox cofactors in a large number of biological processes. We directly attached Br atoms into the conjugated framework of FL to afford FL dibromide (DBFL) and expected the heavy atom effect of Br to facilitate the intersystem crossing of excited FLs ...

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