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Functionalization of 1,3-diphosphacyclobutadiene cobalt complexes via Si–P bond insertion

Rödl, Christian ; Malberg, Jennifer Bissmeyer neé ; Wolf, Robert



Abstract

We report the synthesis of functionalized 1,3-bis(diphosphacyclobutadiene) complexes via the insertion of carbon-oxygen bonds of ethers, esters, aldehydes and amides into the P-Si bond of silylated complexes. Reactions of [K(tol)(2)][Co(eta(4)-P2C2R2)(2)] [[K(tol)(2)] [1a]: R= tBu, [K(tol)(2)][1b]: R= tPent (=tert-pentyl)] with Me3SiCl afford the trimethylsilyl-substituted derivatives ...

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