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Synthesis and photophysical properties of ruthenium(ii) polyimine complexes decorated with flavin

Guo, Huimin ; Zhu, Lijuan ; Dang, Can ; Zhao, Jianzhang ; Dick, Bernhard


A bipyridine ruthenium(ii) complex (Ru-1) with a flavin moiety connected to one of the bipyridine ligands via an acetylene bond was designed and synthesized, and its photophysical properties were investigated. Compared with the tris(bipyridine) Ru(ii) complex (Ru-0), which has an extinction coefficient epsilon = 1.36 x 10(4) M-1 cm(-1) at 453 nm, the introduction of the flavin moiety endows Ru-1 ...


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