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Kinetic and Thermodynamic Control of Nitrile Dissociation in the Complexes (RFe,RC)/(SFe,RC)-[CpFe(Prophos)NCR]X (X = I, PF6) by the Inductive Effect

Brunner, Henri ; Tsuno, Takashi ; Kurosawa, Takaki ; Kitamura, Hikaru ; Ike, Hayato


The chiral-at-metal complexes (R-Fe,R-C )/(S-Fe,R-C )-[CpFe(Prophos)NCR]X (X = I, PF6 ; R = Et, Ph, p-substituted Ph) were prepared, and the diastereomers were separated by fractional crystallization. Eight diastereomerically pure complexes (S-Fe,R-C)-[CpFe(Prophos)NCR]X could be characterized by X-ray crystallography. The kinetics of epimerization with respect to the labile Fe-configuration in ...


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