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Linearly Two-Coordinated Silicon: Transition Metal Complexes with the Functional Groups M≡Si—M and M═Si═M

Ghana, Priyabrata ; Arz, Marius I. ; Chakraborty, Uttam ; Schnakenburg, Gregor ; Filippou, Alexander C.



Abstract

A detailed experimental and theoretical analysis is presented of unprecedented molybdenum complexes featuring a linearly coordinated, multiply bonded silicon atom. Reaction of SiBr2 (SIdipp) (SIdipp = C[N(C6H3-2,6-iPr(2))CH2](2)) with Na[Tp'Mo(CO)(2) (PMe3)] (Na-1) in the ratio 1:2 afforded the reddish-brown metallasilylidyne complex [Tp'(CO)(2)Mo Si-Mo(CO)(2) (PMe3)Tp'] (Tp' = ...

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