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The Different Faces of Photoredox Catalysts: Visible-Light-Mediated Atom Transfer Radical Addition (ATRA) Reactions of Perfluoroalkyl Iodides with Styrenes and Phenylacetylenes

Rawner, Thomas ; Lutsker, Eugen ; Kaiser, Christian A. ; Reiser, Oliver



Abstract

A photoredox-catalyzed procedure for the iodoper-fluoroalkylation of styrenes and phenylacetylenes using readily available copper phenanthroline catalyst is reported. In contrast to commonly employed [Ru(bpy)(3)]Cl-2, [Ru(phen)(3)]Cl-2 or fac-Ir(ppy)(3), [Cu(dap)(2)]Cl is capable to convert styrenes to the corresponding perfluoroalkyl tagged ethylbenzenes, pointing toward an additional role of ...

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