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Hydration and ion association of La3+ and Eu3+ salts in aqueous solution

Friesen, Sergej ; Krickl, Sebastian ; Luger, Magdalena ; Nazet, Andreas ; Hefter, Glenn ; Buchner, Richard



Abstract

Aqueous solutions of five lanthanide salts: LaCl3, La(NO3)(3), La-2(SO4)(3), Eu(NO3)(3) and Eu-2(SO4)(3) have been studied at 25 degrees C by dielectric relaxation spectroscopy over the frequency range 0.05 /GHz 89. Detailed analysis of the solvent-related modes located at higher frequencies showed that both La3+ and Eu3+ are strongly hydrated, even including partial formation of a third ...

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