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Olefin-Stabilized Cobalt Nanoparticles for C=C, C=O, and C=N Hydrogenations

Sandl, Sebastian ; Schwarzhuber, Felix ; Pöllath, Simon ; Zweck, Josef ; Jacobi von Wangelin, Axel



Abstract

The development of cobalt catalysts that combine easy accessibility and high selectivity constitutes a promising approach to the replacement of noble-metal catalysts in hydrogenation reactions. This report introduces a user-friendly protocol that avoids complex ligands, hazardous reductants, special reaction conditions, and the formation of highly unstable pre-catalysts. Reduction of CoBr2 with ...

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