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Synthesis and Reactivity of Nickel-Stabilised μ2 :η2 ,η2 -P2 , As2 and PAs Units

Hierlmeier, Gabriele ; Hinz, Alexander ; Wolf, Robert ; Goicoechea, Jose M.



Abstract

The reactivity of two paramagnetic nickel(I) compounds, CpNi(NHC) (where Cp = cyclopentadienyl; NHC = 1,3-bis(2,4,6-trimethylphenyl) imidazol-2-ylidene (IMes) or 1,3-bis(2,6-diisopropylphenyl) imidazol-2-ylidene (IPr)), towards [Na(dioxane)(x)][PnCO] (Pn = P, As) is described. These reactions afford symmetric bimetallic compounds (mu(2):eta(2),eta(2)-Pn(2)){Ni(NHC)(CO)}(2). Several novel ...

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