Go to content
UR Home

Direct synthesis of an anionic 13-vertex closo-cobaltacarborane cluster

Maier, Thomas M. ; Coburger, Peter ; van Leest, Nicolaas P. ; Hey-Hawkins, Evamarie ; Wolf, Robert


Reaction of 1,2-bis(diphenylphosphino)-ortho-carborane (L) with [K(thf){((Mes)BIAN)Co(eta(4)-cod)}] (1, (Mes)BIAN = bis(mesityliminoace-naphthene)diimine, cod = 1,5-cyclooctadiene) affords an anionic 13-vertex closo-cobaltacarborane cluster (2) in one step. The mechanism of this transformation has been studied by experimental and quantum chemical techniques, which suggest that a series of ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons