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Direct synthesis of an anionic 13-vertex closo-cobaltacarborane cluster

Maier, Thomas M. ; Coburger, Peter ; van Leest, Nicolaas P. ; Hey-Hawkins, Evamarie ; Wolf, Robert



Abstract

Reaction of 1,2-bis(diphenylphosphino)-ortho-carborane (L) with [K(thf){((Mes)BIAN)Co(eta(4)-cod)}] (1, (Mes)BIAN = bis(mesityliminoace-naphthene)diimine, cod = 1,5-cyclooctadiene) affords an anionic 13-vertex closo-cobaltacarborane cluster (2) in one step. The mechanism of this transformation has been studied by experimental and quantum chemical techniques, which suggest that a series of ...

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