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Synthesis, crystal and electronic structures of Pt-rich phosphides EuPt3P and EuPt6P2

Plokhikh, Igor V. ; Khan, Nazir ; Tsirlin, Alexander A. ; Kuznetsov, Alexey N. ; Charkin, Dmitri O. ; Shevelkov, Andrei V. ; Pfitzner, Arno



Abstract

Two new ternary Pt-rich phosphides, EuPt6P2 and EuPt3P, have been prepared via a two-step solid state reaction. Their crystal structures have been determined from powder XRD data. EuPt6P2 is isostructural to SrPt6P2 (cubic, Pa3, a = 8.4603(1) angstrom); its crystal structure comprises corner-sharing Pt6P trigonal prisms hosting Eu2+ cations in the cuboctahedral voids of the framework. EuPt3P is ...

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