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Cobalt-Catalyzed Hydrogenations via Olefin Cobaltate and Hydride Intermediates

Sandl, Sebastian ; Maier, Thomas M. ; van Leest, Nicolaas P. ; Kröncke, Susanne ; Chakraborty, Uttam ; Demeshko, Serhiy ; Koszinowski, Konrad ; de Bruin, Bas ; Meyer, Franc ; Bodensteiner, Michael ; Herrmann, Carmen ; Wolf, Robert ; Jacobi von Wangelin, Axel


Redox noninnocent ligands are a promising tool to moderate electron transfer processes within base-metal catalysts. This report introduces bis(imino)acenaphthene (BIAN) cobaltate complexes as hydrogenation catalysts. Sterically hindered trisubstituted alkenes, imines, and quinolines underwent clean hydrogenation under mild conditions (2-10 bar, 20-80 degrees C) by use of the stable catalyst ...


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