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Flexidentate Coordination Behavior and Chemical Non‐Innocence of a Bis(1,3‐Diphosphacyclobutadiene) Sandwich Anion

Rödl, Christian ; Wolf, Robert


The homoleptic 1,3-diphosphacyclobutadiene sandwich complex [Co(eta(4)-1,3-P(2)C(2)tBu(2))(2)](-) behaved as a versatile and highly flexible metalloligand toward Ni2+, Ru2+, Rh+, and Pd2+ cations, forming a range of unusual oligonuclear compounds. The reaction of [K(thf)(2){Co(eta(4)-1,3-P(2)C(2)tBu(2))(2)}] with [Ni2Cp3]BF4 initially afforded the sigma-complex ...


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