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Synthesis and Characterization of the Tin Iodide Borate Sn3[B3O7]I

Schönegger, Sandra ; Pielnhofer, Florian ; Saxer, Andreas ; Wurst, Klaus ; Huppertz, Hubert


The tin iodide borate Sn-3[B3O7]I was synthesized via a hydrothermal synthesis and crystallizes in the centrosymmetric space group Pbca (no. 61) possessing lattice parameters of a = 1071.8(3), b = 852.3(2), and c = 2016.8(5) pm and Z = 8. Characteristic for the structure are infinite chains along the b axis, built up of three membered B3O8 rings consisting of one BO3 unit and two corner-sharing ...


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