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Dinuclear Design of a Pt(II) Complex Affording Highly Efficient Red Emission: Photophysical Properties and Application in Solution-Processible OLEDs

Shafikov, Marsel Z. ; Daniels, Ruth ; Pander, Piotr ; Dias, Fernando B. ; Williams, J. A. Gareth ; Kozhevnikov, Valery N.


The light-emitting efficiency of luminescent materials is invariably compromised on moving to the red and near-infrared regions of the spectrum due to the transfer of electronic excited-state energy into vibrations. We describe how this undesirable "energy gap law" can be sidestepped for phosphorescent organometallic emitters through the design of a molecular emitter that incorporates two ...


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