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Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt

Ziegler, Christoph G. P. ; Maier, Thomas M. ; Pelties, Stefan ; Taube, Clemens ; Hennersdorf, Felix ; Ehlers, Andreas W. ; Weigand, Jan J. ; Wolf, Robert



Abstract

Rare mono-and diorganopentaphosphido cobalt complexes are accessible by P-P condensation using the unprecedented, reactive cobalt-gallium tetraphosphido complex [K(dme)(2){((Mes)BIAN) Co(mu-eta(4):eta(2)-P-4) Ga(nacnac)}] (2). Compound 2 was prepared in good yield by reaction of [K(Et2O){(MesBIAN) Co(h 4-1,5cod)}] [1, BIAN = bis(mesitylimino) acenaphthene diimine, cod = 1,5-cyclooctadiene] with ...

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