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Insights into the Efficient Intersystem Crossing of Bodipy-Anthracene Compact Dyads with Steady-State and Time-Resolved Optical/Magnetic Spectroscopies and Observation of the Delayed Fluorescence

Wang, Zhijia ; Sukhanov, Andrey A. ; Toffoletti, Antonio ; Sadiq, Farhan ; Zhao, Jianzhang ; Barbon, Antonio ; Voronkova, Violeta K. ; Dick, Bernhard



Abstract

Spin-orbit charge transfer-induced intersystem crossing (SOCT-ISC) is of particular interest for preparation of heavy atom-free triplet photosensitizers. Up to now, examples for SOCT-ISC dyads are limited and electron donor/acceptor SOCT-ISC dyads showing strong visible-light harvesting are rare. Herein, we studied the photophysics of a series of Bodipy-anthracene (BDP-An) compact dyads, ...

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