Low-oxidation state cobalt–magnesium complexes: ion-pairing and reactivity

URN to cite this document:: urn:nbn:de:bvb:355-epub-493963
DOI to cite this document:: 10.5283/epub.49396

Kelly, John A. ; Gramüller, Johannes ; Gschwind, Ruth M.

; Wolf, Robert

Preview

License: Creative Commons: Attribution-Noncommercial 3.0
PDF - Published Version
(1MB)

Anderes - Supplemental Material
Electronic Supplementary Information
(11MB)

Date of publication of this fulltext: 13 Oct 2021 11:11

Alternative links to fulltext:DOI Publisher

Details

Preview

Indexed in

Export bibliographical data

Abstract

Magnesium cobaltates ((Ar)nacnac)MgCo(COD)(2) (1-3) were synthesised by reacting ((Ar)nacnac)MgI(OEt2) with K[Co(eta(4)-COD)(2)] (COD = 1,5-cyclooctadiene) [(Ar)nacnac = CH(ArNCMe)(2); Ar = 2,4,6-Me-3-C6H2 (Mes), 2,6-Et-2-C6H3 (Dep), 2,6-iPr(2)-C(6)H(3)Mes (Dipp)]. Compounds 1-3 form contact ion-pairs in toluene, while solvent separated ion-pairs are formed in THF. The effect of ion-pairing on ...