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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-493963
- DOI to cite this document:
- 10.5283/epub.49396
Abstract
Magnesium cobaltates ((Ar)nacnac)MgCo(COD)(2) (1-3) were synthesised by reacting ((Ar)nacnac)MgI(OEt2) with K[Co(eta(4)-COD)(2)] (COD = 1,5-cyclooctadiene) [(Ar)nacnac = CH(ArNCMe)(2); Ar = 2,4,6-Me-3-C6H2 (Mes), 2,6-Et-2-C6H3 (Dep), 2,6-iPr(2)-C(6)H(3)Mes (Dipp)]. Compounds 1-3 form contact ion-pairs in toluene, while solvent separated ion-pairs are formed in THF. The effect of ion-pairing on ...

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