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Low-oxidation state cobalt–magnesium complexes: ion-pairing and reactivity

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Kelly, John A. ; Gramüller, Johannes ; Gschwind, Ruth M. ; Wolf, Robert
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Date of publication of this fulltext: 13 Oct 2021 11:11


Magnesium cobaltates ((Ar)nacnac)MgCo(COD)(2) (1-3) were synthesised by reacting ((Ar)nacnac)MgI(OEt2) with K[Co(eta(4)-COD)(2)] (COD = 1,5-cyclooctadiene) [(Ar)nacnac = CH(ArNCMe)(2); Ar = 2,4,6-Me-3-C6H2 (Mes), 2,6-Et-2-C6H3 (Dep), 2,6-iPr(2)-C(6)H(3)Mes (Dipp)]. Compounds 1-3 form contact ion-pairs in toluene, while solvent separated ion-pairs are formed in THF. The effect of ion-pairing on ...


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