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An unusual Ni2Si2P8 cluster formed by complexation and thermolysis

Ziegler, Christoph G. P. ; Taube, Clemens ; Kelly, John A. ; Hierlmeier, Gabriele ; Uttendorfer, Maria ; Weigand, Jan J. ; Wolf, Robert



Abstract

[LSi(eta(2)-P-4)] (L = CH[C(Me)N(Dipp)][C(CH2)N(Dipp)], Dipp = 2,6-diisopropylphenyl) forms well-defined 1 : 1 and 2 : 1 complexes with N-heterocyclic carbene nickel fragments. The cluster compound [(IDipp)Ni2P8(SiL)(2)] (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) is selectively formed by thermolysis of the complex [(IDipp)Ni(mu-eta(2:2)-P-4)SiL].


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