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Electric field effect on 31P NMR magnetic shielding

Shenderovich, Ilya G.


Magnetic shielding depends on molecular structure and noncovalent interactions. This study shows that it is also measurably dependent on the electric field generated by surrounding molecules. This effect has been observed explicitly for P-31 nucleus using the adduct under field approach. The results obtained indicate that the field strength experienced by molecules in crystals consisting of ...


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