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Isonitriles as supporting and non-innocent ligands in metal catalysis

Knorn, Matthias ; Lutsker, Eugen ; Reiser, Oliver


Isonitriles, being competent sigma-donors, show a strong aptitude to form transition-state metal complexes. Nevertheless, until the end of the last century, few metal-isonitrile catalyzed processes were known. Only more recently, scientists recognized the considerable potential of isonitriles as ligands in metal catalysis utilizing both commercially available but also specially designed ...


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