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C-Alkylation of alkali metal carbanions with olefins

Mandigma, Mark John P. ; Domański, Michał ; Barham, Joshua P.


C-Alkylations of alkali metal carbanions with olefins, first reported five decades ago, is a class of reaction undergoing a resurgence in organic synthesis in recent years. As opposed to expectations from classical chemistry and transition metal-catalysis, here olefins behave as closed-shell electrophiles. Reactions range from highly reactive alkyllithiums giving rise to anionic polymerization, ...


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