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Triple the fun: tris(ferrocenyl)arene-based gold(i) complexes for redox-switchable catalysis

Straube, Axel ; Coburger, Peter ; Dütsch, Luis ; Hey-Hawkins, Evamarie



Abstract

The modular syntheses ofC(3)-symmetric tris(ferrocenyl)arene-based tris-phosphanes and their homotrinuclear gold(i) complexes are reported. Choosing the arene core allows fine-tuning of the exact oxidation potentials and thus tailoring of the electrochemical response. The tris[chloridogold(i)] complexes were investigated in the catalytic ring-closing isomerisation ofN-(2-propyn-1-yl)benzamide, ...

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