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Ditopic bis(N,N′,N′-substituted 1,2-ethanediamine) ligands: synthesis and coordination chemistry

Rösch, Andreas ; Herzog, Christoph M. ; Schreiner, Simon H. F. ; Görls, Helmar ; Kretschmer, Robert


The synthesis of two different types of bis(N,N',N'-substituted 1,2-ethanediamine)s, bridged either through the secondary (type 1) or tertiary (type 2) amine groups is reported. Selected protio-ligands have been applied in subsequent metallation reactions using aluminium, magnesium, tin, and zinc sources allowing to isolate five mononuclear and eight dinuclear complexes. All complexes have been ...


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