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From S–O–S to B–O–S to B–O–B Bridges: Ba[B(S2O7)2]2 as a Model System for the Structural Diversity in Borosulfate Chemistry

Netzsch, Philip ; Pielnhofer, Florian ; Höppe, Henning A.


Various different possible connection patterns of sulfate and borate tetrahedra enable a vast structural diversity in borosulfates, a rather new class of silicate-analogous compounds. Here we unravel a direct relationship from S-O-S to B-O-S to B-O-B bridges for the first time in borosulfate chemistry. Solvothermal synthesis in pure oleum (65% SO3) yielded the first alkaline earth metal ...


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