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Copper Makes the Difference: Visible Light-Mediated Atom Transfer Radical Addition Reactions of Iodoform with Olefins

Engl, Sebastian ; Reiser, Oliver


Herein, we report a visible light-mediated copper-catalyzed protocol enabling the highly economic, vicinal difunctionalization of olefins utilizing the readily available bulk chemical iodoform. This protocol is characterized by high yields under environmentally benign reaction conditions and allows the regioselective and chemoselective functionalization of activated double bonds. Besides the ...


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