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The specific features of phononic and magnetic subsystems of type-VII clathrate EuNi2P4

Novikov, V. V. ; Bud’ko, S. L. ; Matovnikov, A. V. ; Mitroshenkov, N. V. ; Pilipenko, K. S. ; Konoplin, N. A. ; Plokhikh, I. V. ; Pfitzner, A. ; Shevelkov, A. V.



Abstract

A type-VII clathrate with a Eu(2+)guest embedded into a Ni-P covalent framework, EuNi2P4, was synthesized by a standard two-stage ampoule synthesis and confirmed to crystallize in the orthorhombic space groupFdddwith unit cell parametersa= 5.1829(1) angstrom,b= 9.4765(1) angstrom, andc= 18.9900(1) angstrom. A general technique for studying the lattice and magnetic properties of REE containing ...

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