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Synthesis, electronic structure and physical properties of two new layered compounds, EuFAgSe and EuFAg1−δTe, featuring the active redox pair Eu2+/Ag+

Plokhikh, Igor V. ; Tsirlin, Alexander A. ; Heletta, Lukas ; Klenner, Steffen ; Charkin, Dmitri O. ; Kuznetsov, Alexey N. ; Shevelkov, Andrei V. ; Pöttgen, Rainer ; Pfitzner, Arno


Systematic studies of the ZrCuSiAs (also LaOAgS or 1111) structure type resulted in the synthesis of two new fluoride chalcogenides, EuFAgSe and EuFAg1-delta Te, whereas their sulfide analog, EuFAgS, could not be obtained. Both new compounds are tetragonal,P4/nmm, with cell parametersa= 4.1542(1) angstrom,c= 9.2182(1) angstrom for the selenide anda= 4.3255(1) angstrom,c= 9.5486(1) angstrom for ...


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