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What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts

Jansen, Dennis ; Gramüller, Johannes ; Niemeyer, Felix ; Schaller, Torsten ; Letzel, Matthias C. ; Grimme, Stefan ; Zhu, Hui ; Gschwind, Ruth M. ; Niemeyer, Jochen



Abstract

Organocatalysis has revolutionized asymmetric synthesis. However, the supramolecular interactions of organocatalysts in solution are often neglected, although the formation of catalyst aggregates can have a strong impact on the catalytic reaction. For phosphoric acid based organocatalysts, we have now established that catalyst-catalyst interactions can be suppressed by using macrocyclic ...

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